I was toying with having a character (that has a lot of free knowledge skill points) taking Technical School Education, and picking up a bunch of professions which could either be somewhat useful, or useful as parts of infiltration/disguises/cons. An obvious one would be 'Janitorial Science' (because who looks hard at a cleaner who seems to know what they are doing). A bit of 'cook' just to avoid Stuffer Shack for meals.
Do you have professional knowledge skills that you have found fun, useful, or interesting?